What is Biodiesel.....

study image
Biodiesel, which often has the familiar smell of putty or linseed oil, is a liquid with a viscosity similar to that of petrodiesel and is clear amber-yellow in colour. It is fuel made from renewable resources such as vegetable oils or animal fats and the transesterification can be made to look simple:

Vegetable oil + methanol = biodiesel

but this does not happen all at once!

The following diagram shows the three stages needed to complete the reaction and that all the processes are reversible.

Click on the above diagram for more details

Reversible processes need a driving force to get them to their equillibrium position - for this process the easiest method is to add an excess of methanol, which shifts the balance over to make biodiesel.

It is only by using excess methanol that the 96.5% EN14214 standard can be achieved. Some of the impurities can be extracted with post processing, but the best way to make good fuel is to get the chemistry to equilibrium, ensuring the best yield, purest product, and therefore easiest separations.

Philosophy that makes the difference.....

All the systems developed at BHR Biofuels Ltd have been designed through the philosophy of Process Intensification. A full understanding of all aspects of the process is essential, including:-

Chemistry – Rates of reaction have been measured, the by-products assessed and impurities mapped to understand the limits of the reaction. Also a variety of feedstocks have been tested including rape (cold and hot pressed), Soy bean, sunflower, tallow (refined and unrefined, from pig and cow sources), waste vegetable oil (a variety of sources), and Palm (refined, un-refined and crude).

Heat transfer – The temperature at which the process is carried out is not that important (the chemistry is still fast at room temperature). Most companies think high temperature always makes a big difference, but this process is mass-transfer limited. Raising the temperature costs a lot of money and only succeeds in lowering the viscosity slightly and increasing mass transfer rates by perhaps 10% for every 10°C. The real gains in rate are made by getting the mixing right (see below). We have set the temperature to be that which makes most sense for the upstream and downstream processing.

Mixing – Mixing affects the mass transfer rates and therefore rates of reaction. It is the thorough understanding of mixing processes (from macro-mixing and meso-mixing to micro-mixing) which enables the process rate to be accelerated to the impressive results obtained by our products.

Process flow-regime – Running in a continuous system (see the BHR-70T) or a batch system (see the BHR-JBR) require individual solutions for making best use of the mixing energy to give the fastest process rates.

Costs of operation – Costing the energy, personnel and time requirements for each stage of the process is a key part of achieving viable intensified chemical processes. Over the past 14 years BHR Biofuels Ltd has gained the experience and skills to successfully implement these processes.

When you talk to us about the many innovative features of our processors you will quickly realise the effort that has gone into making these systems the most cost effective solutions.

 

© 2007 BHR Biofuels Ltd

Cranfield, Bedfordshire, MK43 0AJ
United Kingdom
Tel: +44 (0)1234 750422